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Copper-catalyzed oxidative phosphonation of 3,4-dihydro-1,4-benzoxazin-2-ones

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Abstract

A straight-forward and atom-economical Cu(II)/PBQ-catalyzed oxidative phosphonation of 3,4-dihydro-1,4-benzoxazin-2-ones has been developed through an OEO involving oxidative Pudovik reaction. The experiments are performed under mild reaction conditions to construct new Csp3–P bonds and provide a new opportunity to obtain potentially bioactive α-aminophosphonates with a novel structure.

Graphical abstract: Copper-catalyzed oxidative phosphonation of 3,4-dihydro-1,4-benzoxazin-2-ones

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Publication details

The article was received on 29 Sep 2018, accepted on 05 Nov 2018 and first published on 05 Nov 2018


Article type: Research Article
DOI: 10.1039/C8QO01049H
Citation: Org. Chem. Front., 2018, Advance Article
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    Copper-catalyzed oxidative phosphonation of 3,4-dihydro-1,4-benzoxazin-2-ones

    J. Wang, J. Li, Y. Wei, J. Yang and C. Huo, Org. Chem. Front., 2018, Advance Article , DOI: 10.1039/C8QO01049H

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