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Transition metal-free base-promoted arylation of sulfenate anions with diaryliodonium salts

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Abstract

A transition metal-free, base-promoted arylation of general sulfenate anions with diaryliodonium salts as an aryl source was developed under mild conditions. Retro-Michael reaction and C–S bond formation were involved in this transformation leading to diaryl and aryl alkyl sulfoxides in good yields. This procedure has general substrate scope and is easy to scale-up.

Graphical abstract: Transition metal-free base-promoted arylation of sulfenate anions with diaryliodonium salts

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Publication details

The article was received on 23 Aug 2018, accepted on 31 Oct 2018 and first published on 01 Nov 2018


Article type: Research Article
DOI: 10.1039/C8QO00914G
Citation: Org. Chem. Front., 2018, Advance Article
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    Transition metal-free base-promoted arylation of sulfenate anions with diaryliodonium salts

    L. Wang, M. Chen and J. Zhang, Org. Chem. Front., 2018, Advance Article , DOI: 10.1039/C8QO00914G

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