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Issue 21, 2018
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DDQ-mediated regioselective C–S bond formation: efficient access to allylic sulfides

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Abstract

A protocol for the synthesis of allylic sulfides from simple allylic hydrocarbons with thiophenol derivatives via a DDQ-mediated oxidative dehydrogenation strategy is described. This reaction possesses good functional group compatibility, broad substrate scope, and high atom- and step-economy. Moreover, the synthetic utility of this method can be highlighted by its application in the synthesis of versatile organo-sulfur compounds.

Graphical abstract: DDQ-mediated regioselective C–S bond formation: efficient access to allylic sulfides

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Publication details

The article was received on 31 Jul 2018, accepted on 15 Sep 2018 and first published on 18 Sep 2018


Article type: Research Article
DOI: 10.1039/C8QO00799C
Citation: Org. Chem. Front., 2018,5, 3158-3162
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    DDQ-mediated regioselective C–S bond formation: efficient access to allylic sulfides

    C. Li, J. Li, C. Tan, W. Wu and H. Jiang, Org. Chem. Front., 2018, 5, 3158
    DOI: 10.1039/C8QO00799C

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