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Issue 10, 2018
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Palladium-catalyzed intermolecular dearomatic allenylation of hydrocycloalk[b]indoles with 2,3-allenyl carbonates

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Abstract

A palladium-catalyzed intermolecular dearomatic allenylation of hydrocycloalk[b]indoles with 2,3-allenyl carbonates has been developed, providing access to functionalized allenes containing an indoline unit under optimized conditions. Both terminal and non-terminal allenes could react smoothly with an exclusive chemoselectivity and good yields by applying different reaction parameters.

Graphical abstract: Palladium-catalyzed intermolecular dearomatic allenylation of hydrocycloalk[b]indoles with 2,3-allenyl carbonates

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Article information


Submitted
10 Feb 2018
Accepted
14 Mar 2018
First published
15 Mar 2018

Org. Chem. Front., 2018,5, 1664-1669
Article type
Research Article

Palladium-catalyzed intermolecular dearomatic allenylation of hydrocycloalk[b]indoles with 2,3-allenyl carbonates

R. Gao, Y. Zhai, S. You and S. Ma, Org. Chem. Front., 2018, 5, 1664
DOI: 10.1039/C8QO00163D

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