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Issue 10, 2018
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High quantum yield and unusual photoluminescence behaviour in tetrahedral manganese(II) based on hybrid compounds

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Abstract

Two novel tetrahedral manganese(II) complexes, (N-methylpiperidinium)MnCl4 (1) and (N-methylpyrrolidinium)MnCl4 (2), with clearly distinct fluorescence characteristics were synthesized through organic cation modulation. Compound 1 exhibits prominent green luminescence with a high quantum yield of 79.37% and 2 emits unusual red emission at 611 nm.

Graphical abstract: High quantum yield and unusual photoluminescence behaviour in tetrahedral manganese(ii) based on hybrid compounds

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Publication details

The article was received on 31 Jul 2018, accepted on 01 Sep 2018 and first published on 03 Sep 2018


Article type: Research Article
DOI: 10.1039/C8QI00793D
Citation: Inorg. Chem. Front., 2018,5, 2615-2619
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    High quantum yield and unusual photoluminescence behaviour in tetrahedral manganese(II) based on hybrid compounds

    Y. Wei, J. Jing, C. Shi, H. Ye, Z. Wang and Y. Zhang, Inorg. Chem. Front., 2018, 5, 2615
    DOI: 10.1039/C8QI00793D

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