Issue 6, 2018
From the journal:

Inorganic Chemistry Frontiers

In situ synthesis and photocatalytic mechanism of a cyano bridged Cu(i) polymer†

Shixiong Li, ORCID logo a   Chaohai Wei,*a   Yun Hu,*a   Haizhen Wub  and  Fusheng Lic  

* Corresponding authors

a School of Environment and Energy, South China University of Technology, Guangzhou, P. R. China
E-mail: cechwei@scut.edu.cn@163.com, huyun@scut.edu.cn

b School of Biology and Biological Engineering, South China University of Technology, Guangzhou, P. R. China

c River Basin Research Center, Gifu University, 1-1 Yanagido, Gifu 501-1193, Japan

Abstract

A one-dimensional copper(I) nanorod polymer [Cu(L)2·(CN)]n (1) (L = 4(3H)-quinazolone), was formed in situ by C–C bond cleavage of acetonitrile. The in situ synthesis of 1 was analyzed using electron paramagnetic resonance (EPR) spectroscopy and electrospray ionization mass spectrometry (ESI-MS) and its methylene blue (MB) photocatalytic degradation mechanism was revealed from density functional theory (DFT) calculations. The results are helpful for the in situ synthesis of –CN complexes.

Graphical abstract: In situ synthesis and photocatalytic mechanism of a cyano bridged Cu(i) polymer

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C8QI00205C
Article type
Research Article
Submitted
07 Mar 2018
Accepted
27 Mar 2018
First published
28 Mar 2018

Inorg. Chem. Front., 2018,5, 1282-1287

Permissions

Request permissions

In situ synthesis and photocatalytic mechanism of a cyano bridged Cu(I) polymer

S. Li, C. Wei, Y. Hu, H. Wu and F. Li, Inorg. Chem. Front., 2018, 5, 1282 DOI: 10.1039/C8QI00205C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements