Ethylene glycol (EG) as a universal solvent is used to reproducibly synthesize zeolitic tetrazolate imidazolate frameworks (ZTIF-11 to -13) in high yields. The phase-pure frl-type ZTIF-11 is confirmed to be permanently porous and shows high chemical stability as well as remarkable performance in the selective separation of CO2 at ambient temperature.
M. Li, H. Zhang, F. Wang and J. Zhang, Inorg. Chem. Front., 2018, 5, 675 DOI: 10.1039/C7QI00765E
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