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Issue 41, 2018
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Choosing the ideal photoinitiator for free radical photopolymerizations: predictions based on simulations using established data

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Abstract

We present a tool for predicting the initiation efficiency of various type 1 (α-cleavage) photoinitiators for free radical photopolymerization. The amount of initiated polymer chains is crucial for the successful outcome of radical polymerizations. This is based on a subtle combination of intrinsic photoinitiator characteristics, i.e. quantum yields for dissociation, the absorption spectrum of the initiator in terms of its absorption bands and the corresponding absorption coefficients (ε), the rate constants of the primary radicals toward the monomer, and side reactions such as oxygen quenching. Equally important are the emission properties of the utilized light source (irradiation wavelengths, light intensity). We highlight that a balanced combination of all these factors is crucial for achieving optimal initiation performance.

Graphical abstract: Choosing the ideal photoinitiator for free radical photopolymerizations: predictions based on simulations using established data

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Publication details

The article was received on 13 Aug 2018, accepted on 17 Sep 2018 and first published on 17 Sep 2018


Article type: Paper
DOI: 10.1039/C8PY01195H
Citation: Polym. Chem., 2018,9, 5107-5115
  • Open access: Creative Commons BY-NC license
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    Choosing the ideal photoinitiator for free radical photopolymerizations: predictions based on simulations using established data

    A. Eibel, D. E. Fast and G. Gescheidt, Polym. Chem., 2018, 9, 5107
    DOI: 10.1039/C8PY01195H

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