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Issue 3, 2019
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Recent developments in photochemical reactions of diazo compounds

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Abstract

Diazo compounds are among the most important building blocks in organic synthesis. Generally, their photoinitiated, thermal, or transition metal catalyzed decomposition yields the corresponding carbenes or metal carbenoids, which subsequently undergo various transformations. Modern chemistry of diazo compounds is dominated by transition metal catalysis, leaving both catalyzed and non-catalyzed phototransformations of these reagents behind. Recently, photoinitiated reactions of diazo compounds have experienced a revival of interest due to the increased understanding of modern photochemistry. This mini-review covers recently published (year >2000) reports on the reactivity of diazo compounds under light irradiation.

Graphical abstract: Recent developments in photochemical reactions of diazo compounds

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Publication details

The article was received on 31 Oct 2018, accepted on 07 Dec 2018 and first published on 07 Dec 2018


Article type: Review Article
DOI: 10.1039/C8OB02703J
Citation: Org. Biomol. Chem., 2019,17, 432-448

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    Recent developments in photochemical reactions of diazo compounds

    Ł. W. Ciszewski, K. Rybicka-Jasińska and D. Gryko, Org. Biomol. Chem., 2019, 17, 432
    DOI: 10.1039/C8OB02703J

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