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Rh-Catalyzed diastereoselective desymmetrization of enone tethered-cyclohexadienones via tandem arylative cyclization

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Abstract

The rhodium-catalyzed arylative cyclization of enone tethered-cyclohexadienones has been developed with high efficiency, thus providing cis-fused bicyclic enones in good yields and with excellent diastereoselectivities. Furthermore, this mild transformation has a broad range of substrate scope and excellent functional group tolerance. In addition, bicyclic products have an enone functionality, which can be a synthetically valuable handle for further transformations.

Graphical abstract: Rh-Catalyzed diastereoselective desymmetrization of enone tethered-cyclohexadienones via tandem arylative cyclization

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Publication details

The article was received on 15 Sep 2018, accepted on 04 Oct 2018 and first published on 05 Oct 2018


Article type: Paper
DOI: 10.1039/C8OB02284D
Citation: Org. Biomol. Chem., 2018, Advance Article
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    Rh-Catalyzed diastereoselective desymmetrization of enone tethered-cyclohexadienones via tandem arylative cyclization

    S. B. Jadhav, S. B. Thopate, J. B. Nanubolu and R. Chegondi, Org. Biomol. Chem., 2018, Advance Article , DOI: 10.1039/C8OB02284D

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