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Issue 46, 2018
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A removable functional group strategy for regiodivergent Wittig rearrangement products

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Abstract

[1,2] and [2,3] Wittig rearrangements are competing reaction pathways, often leading to uncontrollable product distribution. We employ a single removable functional group to fulfill the dual role of attaining a reversible [2,3] and stabilizing radical intermediate for the [1,2] path to obtain both the Wittig products selectively for a broad range of substrates.

Graphical abstract: A removable functional group strategy for regiodivergent Wittig rearrangement products

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Publication details

The article was received on 08 Sep 2018, accepted on 02 Nov 2018 and first published on 03 Nov 2018


Article type: Communication
DOI: 10.1039/C8OB02221F
Citation: Org. Biomol. Chem., 2018,16, 8922-8926
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    A removable functional group strategy for regiodivergent Wittig rearrangement products

    M. N. Alam, L. K. M. and P. Maity, Org. Biomol. Chem., 2018, 16, 8922
    DOI: 10.1039/C8OB02221F

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