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Issue 40, 2018
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Base-mediated [2 + 4] cycloadditions of in situ formed azaoxyallyl cations with N-(2-chloromethyl)aryl amides

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Abstract

A base-mediated [2 + 4] annulation of in situ formed azaoxyallyl cations with in situ generated aza-oQMs has been realized. This one-pot cycloaddition process assembled the corresponding 1,4-dihydro-2H-benzo[d][1,3]oxazines in moderate to good yields (up to 99% yield).

Graphical abstract: Base-mediated [2 + 4] cycloadditions of in situ formed azaoxyallyl cations with N-(2-chloromethyl)aryl amides

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Supplementary files

Article information


Submitted
04 Sep 2018
Accepted
24 Sep 2018
First published
25 Sep 2018

Org. Biomol. Chem., 2018,16, 7336-7339
Article type
Communication

Base-mediated [2 + 4] cycloadditions of in situ formed azaoxyallyl cations with N-(2-chloromethyl)aryl amides

Q. Jin, M. Gao, D. Zhang, C. Jiang, N. Yao and J. Zhang, Org. Biomol. Chem., 2018, 16, 7336
DOI: 10.1039/C8OB02176G

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