Issue 28, 2018
From the journal:

Organic & Biomolecular Chemistry

Carbenium ion formation by fragmentation of electrochemically generated oxonium ions†

Anna Lielpetere ORCID logo a  and  Aigars Jirgensons ORCID logo *a  

* Corresponding authors

a Latvian Institute of Organic Synthesis, Aizkraukles 21, Riga, LV-1006, Latvia
E-mail: aigars@osi.lv

Abstract

Fragmentation of electrochemically generated oxonium ions can be exploited to form carbenium ions at a low oxidation potential in the presence of a nucleophile. The application of this concept is demonstrated for the allylation of carbenium ions generated by the anodic oxidation of stannylmethylethers.

Graphical abstract: Carbenium ion formation by fragmentation of electrochemically generated oxonium ions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C8OB01339J
Article type
Communication
Submitted
07 Jun 2018
Accepted
27 Jun 2018
First published
27 Jun 2018

Org. Biomol. Chem., 2018,16, 5094-5096

Permissions

Request permissions

Carbenium ion formation by fragmentation of electrochemically generated oxonium ions

A. Lielpetere and A. Jirgensons, Org. Biomol. Chem., 2018, 16, 5094 DOI: 10.1039/C8OB01339J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements