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Issue 5, 2018
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Highly chemoselective intermolecular cross-benzoin reactions using an ad hoc designed novel N-heterocyclic carbene catalyst

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Abstract

The design of a novel N-heterocyclic carbene catalyst incorporating a bulky yet highly electron-deficient N-aryl substituent has allowed the development of an efficient protocol for the first highly chemoselective intermolecular benzoin condensations between two non-identical aromatic aldehydes.

Graphical abstract: Highly chemoselective intermolecular cross-benzoin reactions using an ad hoc designed novel N-heterocyclic carbene catalyst

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Article information


Submitted
05 Dec 2017
Accepted
04 Jan 2018
First published
10 Jan 2018

Org. Biomol. Chem., 2018,16, 780-786
Article type
Paper

Highly chemoselective intermolecular cross-benzoin reactions using an ad hoc designed novel N-heterocyclic carbene catalyst

E. G. Delany and S. J. Connon, Org. Biomol. Chem., 2018, 16, 780
DOI: 10.1039/C7OB03005C

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