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Spin-polarized Fermi surface, hole-doping and band gap in graphene with boron impurities.

Abstract

Embedding foreign atoms in graphene and interchanging the underlying substrate are proven to be efficient methods for manipulating the properties of graphene. Combining ARPES experiments with DFT calculations we show that boron-doped graphene (B-graphene) grown on a Co(0001) substrate by chemical vapor deposition (CVD) becomes hole doped and its Fermi surface near the K-point reveals strongly spin-polarized states. The latter stem from the spin-polarized mini Dirac cone that is an intrinsic two-dimensional feature of the graphene/Co(0001) interface and is formed by mixture of C 2pz and Co 3d states. Since the CVD method allows to get up to 20 at.% of incorporated B atoms, this provides a certain flexibility for handling the spin-polarized properties of the system. We also show that the bonding of the B-graphene layer to the Co(0001) substrate can be released by intercalation of Li into the interface. This allows to explore the doping effect in details. Finally, our ARPES data indicate a gap opening in the Dirac cone as a result of the highly unbalanced boron concentrations in the two graphene sublattices

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Publication details

The article was accepted on 04 Nov 2018 and first published on 07 Nov 2018


Article type: Paper
DOI: 10.1039/C8NR08339H
Citation: Nanoscale, 2018, Accepted Manuscript
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    Spin-polarized Fermi surface, hole-doping and band gap in graphene with boron impurities.

    A. Fedorov, L. V. Yashina, O. Y. Vilkov, C. Laubschat, D. V. Vyalikh and D. Yu. Usachov, Nanoscale, 2018, Accepted Manuscript , DOI: 10.1039/C8NR08339H

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