Issue 6, 2018
From the journal:

Natural Product Reports

Enantioselective palladium-catalyzed allylic alkylation reactions in the synthesis of Aspidosperma and structurally related monoterpene indole alkaloids

Beau P. Pritchett ORCID logo a  and  Brian M. Stoltz ORCID logo *a  

* Corresponding authors

a The Warren and Katharine Schlinger Laboratory for Chemistry and Chemical Engineering, Division of Chemistry and Chemical Engineering, California Institute of Technology, 1200 E. California Blvd, Pasadena, CA 91125, USA
E-mail: Stoltz@caltech.edu

Abstract

Covering: up to the end of 2017

Enantioselective Pd-catalyzed allylic alkylations of prochiral enolates represent a powerful tool for the construction of all-carbon quaternary stereocenters. This review describes the emergence of such reactions as strategic linchpins that enable efficient, stereocontrolled syntheses of Aspidosperma and related monoterpene indole alkaloids.

Graphical abstract: Enantioselective palladium-catalyzed allylic alkylation reactions in the synthesis of Aspidosperma and structurally related monoterpene indole alkaloids

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C7NP00069C
Article type
Review Article
Submitted
23 Dec 2017
First published
16 Apr 2018

Nat. Prod. Rep., 2018,35, 559-574

Author version available


Download author version (PDF)

Permissions

Request permissions

Enantioselective palladium-catalyzed allylic alkylation reactions in the synthesis of Aspidosperma and structurally related monoterpene indole alkaloids

B. P. Pritchett and B. M. Stoltz, Nat. Prod. Rep., 2018, 35, 559 DOI: 10.1039/C7NP00069C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements