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Green catalysis for the selective oxidation of sulfides with high turnover numbers in water at room temperature

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Abstract

A hybrid catalyst based on monoprotonated divanadium-substituted phosphotungstate ([γ-HPV2W10O40]4−) was synthesized and used for the selective oxidation of sulfides. The catalytic system was carried out in water with hydrogen peroxide at room temperature. Unprecedented turnover numbers (TONs) for all substrates were obtained, which are much higher than previous reports.

Graphical abstract: Green catalysis for the selective oxidation of sulfides with high turnover numbers in water at room temperature

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Publication details

The article was received on 12 Oct 2018, accepted on 06 Nov 2018 and first published on 07 Nov 2018


Article type: Letter
DOI: 10.1039/C8NJ05170D
Citation: New J. Chem., 2018, Advance Article
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    Green catalysis for the selective oxidation of sulfides with high turnover numbers in water at room temperature

    W. Zhao, C. Yang, H. Sun, Z. Cheng and T. Chang, New J. Chem., 2018, Advance Article , DOI: 10.1039/C8NJ05170D

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