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Issue 20, 2018
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Covalent bond formation via a [2+2] cycloaddition reaction as a tool to alter thermal expansion parameters of organic co-crystals

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Abstract

The thermal expansion properties of a co-crystal containing the photodimerization product rctt-tetrakis(4-pyridyl)cyclobutane and resorcinol is reported. The photocycloaddition reaction generates new carbon–carbon bonds in the solid, resulting in a significant decrease in the ability of the co-crystal to expand along the direction of the newly formed bonds.

Graphical abstract: Covalent bond formation via a [2+2] cycloaddition reaction as a tool to alter thermal expansion parameters of organic co-crystals

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Publication details

The article was received on 31 Jul 2018, accepted on 13 Sep 2018 and first published on 14 Sep 2018


Article type: Letter
DOI: 10.1039/C8NJ03815E
Citation: New J. Chem., 2018,42, 16460-16463

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    Covalent bond formation via a [2+2] cycloaddition reaction as a tool to alter thermal expansion parameters of organic co-crystals

    K. M. Hutchins, D. K. Unruh and R. H. Groeneman, New J. Chem., 2018, 42, 16460
    DOI: 10.1039/C8NJ03815E

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