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Issue 21, 2018
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Constructing a self-assembling C3-symmetric covalently linked (fused) donor–acceptor-type molecule containing a hexaazatriphenylene core

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Abstract

A C3-symmetric covalently linked (fused) molecule, HAT-IPN, comprising a 13 fused ring system was synthesized by a condensation-cyclisation reaction between hexaazatriphenylenehexacarboxylic acid trisanhydride and 4,5-diamino-1,2-dioctyloxybenzene. This fused system exhibits ambipolar behaviour due to an n-type HAT-core at the center and three outer p-type fused dialkoxybenzimidazole moieties, which is confirmed by cyclic voltammetry. The self-assembling nature of this disc-shaped donor–acceptor type system is evident in 13C NMR spectroscopy, dynamic light scattering studies, differential scanning calorimetry and atomic force microscopy (AFM) images, which illustrate the formation of the one-dimensional aggregates both in solution and in the film state; indicating its potential as an active component in organic electronic devices.

Graphical abstract: Constructing a self-assembling C3-symmetric covalently linked (fused) donor–acceptor-type molecule containing a hexaazatriphenylene core

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Publication details

The article was received on 30 Jul 2018, accepted on 24 Sep 2018 and first published on 25 Sep 2018


Article type: Paper
DOI: 10.1039/C8NJ03793K
Citation: New J. Chem., 2018,42, 17700-17707

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    Constructing a self-assembling C3-symmetric covalently linked (fused) donor–acceptor-type molecule containing a hexaazatriphenylene core

    V. J. Bhanvadia, A. L. Patel and S. S. Zade, New J. Chem., 2018, 42, 17700
    DOI: 10.1039/C8NJ03793K

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