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Issue 23, 2018
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A new multi-analyte fluorogenic sensor for efficient detection of Al3+ and Zn2+ ions based on ESIPT and CHEF features

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Abstract

The fluorogenic chemosensor 3-(((2-hydroxy-4-methylphenyl)imino)methyl)-[1,1′-biphenyl]-4-ol (H2L) efficiently detects Zn2+ and Al3+ ions and subsequently fluoride ion in methanol–water (4/1, v/v, pH = 7.2) solution. The probe itself is non-emissive but upon treatment with Al3+ and Zn2+, it exhibits high fluorescence emission at two different wavelengths of 546 nm and 529 nm, respectively. Both excited-state intramolecular proton transfer (ESIPT) and chelation enhanced fluorescence (CHEF) processes play important roles in the enhancement of fluorescence intensity. Chelation of Zn2+ and Al3+ with the probe (H2L) inhibits C[double bond, length as m-dash]N isomerization and ESIPT which consequently enhances the emission intensity. The emission intensity of H2L–Al3+ is selectively quenched upon titration with F anions. The structure of the probe is confirmed by the single crystal X-ray diffraction method. The electronic structure and sensing mechanism of the probe (H2L) are supported by density functional theory (DFT) and time-dependent density functional theory (TDDFT).

Graphical abstract: A new multi-analyte fluorogenic sensor for efficient detection of Al3+ and Zn2+ ions based on ESIPT and CHEF features

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Publication details

The article was received on 27 Jun 2018, accepted on 24 Oct 2018 and first published on 24 Oct 2018


Article type: Paper
DOI: 10.1039/C8NJ03191F
Citation: New J. Chem., 2018,42, 19076-19082
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    A new multi-analyte fluorogenic sensor for efficient detection of Al3+ and Zn2+ ions based on ESIPT and CHEF features

    L. Patra, S. Das, S. Gharami, K. Aich and T. K. Mondal, New J. Chem., 2018, 42, 19076
    DOI: 10.1039/C8NJ03191F

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