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Issue 14, 2018
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Ruthenium-catalyzed synthesis of 1,3,5-triazin-2(1H)-ones and dihydro[1,3,5]triazino[1,2-a]benzimidazoles from alcohols and guanides

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Abstract

An efficient ruthenium-catalyzed synthesis of tri-substituted 1,3,5-triazinones from alcohols and guanylureas under mild conditions has been developed. The scope of both the alcohols and guanylureas in the reaction is demonstrated. This ruthenium-catalyzed ring-forming process can be successfully extended to 2-guanidinobenzimidazoles to afford substituted dihydro[1,3,5]triazino[1,2-a]benzimidazoles.

Graphical abstract: Ruthenium-catalyzed synthesis of 1,3,5-triazin-2(1H)-ones and dihydro[1,3,5]triazino[1,2-a]benzimidazoles from alcohols and guanides

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Publication details

The article was received on 26 Apr 2018, accepted on 13 Jun 2018 and first published on 15 Jun 2018


Article type: Paper
DOI: 10.1039/C8NJ02035C
Citation: New J. Chem., 2018,42, 11905-11907
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    Ruthenium-catalyzed synthesis of 1,3,5-triazin-2(1H)-ones and dihydro[1,3,5]triazino[1,2-a]benzimidazoles from alcohols and guanides

    M. Zeng, Z. P. Xie, D. Cui and C. Zhang, New J. Chem., 2018, 42, 11905
    DOI: 10.1039/C8NJ02035C

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