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Issue 22, 2018
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IClick cycloaddition reaction of light-triggered manganese(I) carbonyl complexes

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Abstract

Mono- and binuclear blue-light-induced CO-releasing molecules based on a fac-MnBr(CO)3 moiety and bearing benzimidazole ligands furnished with either a sulfonate or phosphonium group were synthesized. The effect of the ancillary ligand (Br and NCS) on the CO releasing properties was studied and compared with that of the triazolate complex synthesized by the free catalyst [3+2] cycloaddition iClick reaction. An extension of the iClick reaction to the binuclear complex was successful. The assignment of electronic transitions was done by TDDFT. The photoprocess of the binuclear complexes was faster than that of the mononuclear complex.

Graphical abstract: IClick cycloaddition reaction of light-triggered manganese(i) carbonyl complexes

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Publication details

The article was received on 16 Apr 2018, accepted on 07 Oct 2018 and first published on 08 Oct 2018


Article type: Paper
DOI: 10.1039/C8NJ01838C
Citation: New J. Chem., 2018,42, 18418-18425

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    IClick cycloaddition reaction of light-triggered manganese(I) carbonyl complexes

    A. M. Mansour and A. Friedrich, New J. Chem., 2018, 42, 18418
    DOI: 10.1039/C8NJ01838C

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