Issue 11, 2018
From the journal:

New Journal of Chemistry

Stereoselective synthesis of cyclopentafullerenes: the reaction of [60]fullerene with aldehydes and triethylamine promoted by magnesium perchlorate†

Meng Zhang,‡a   Hong-Yu Zhang,‡a   Hui-Juan Wang,b   Fa-Bao Li, ORCID logo *a   Yongshun Huang, ORCID logo a   Li Liu,*a   Chao-Yang Liu,*b   Abdullah M. Asiri ORCID logo c  and  Khalid A. Alamryc  

* Corresponding authors

a Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Key Laboratory of Green Preparation and Application for Functional Materials, Ministry of Education, and School of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062, P. R. China
E-mail: lfb0615@hubu.edu.cn, liulihubei@hubu.edu.cn

b State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Center for Magnetic Resonance, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071, P. R. China
E-mail: chyliu@wipm.ac.cn

c Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia

Abstract

The magnesium perchlorate-mediated reaction of [60]fullerene with aldehydes and triethylamine under air conditions afforded a series of rare cyclopentafullerenes in moderate to good yields with high stereoselectivity. A plausible reaction mechanism was suggested to elucidate the formation of cyclopentafullerenes.

Graphical abstract: Stereoselective synthesis of cyclopentafullerenes: the reaction of [60]fullerene with aldehydes and triethylamine promoted by magnesium perchlorate

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Article information

DOI
https://doi.org/10.1039/C8NJ01578C
Article type
Paper
Submitted
31 Mar 2018
Accepted
26 Apr 2018
First published
30 Apr 2018

New J. Chem., 2018,42, 9291-9299

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Stereoselective synthesis of cyclopentafullerenes: the reaction of [60]fullerene with aldehydes and triethylamine promoted by magnesium perchlorate

M. Zhang, H. Zhang, H. Wang, F. Li, Y. Huang, L. Liu, C. Liu, A. M. Asiri and K. A. Alamry, New J. Chem., 2018, 42, 9291 DOI: 10.1039/C8NJ01578C

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