Jump to main content
Jump to site search

Issue 12, 2018
Previous Article Next Article

Pd nanoparticles supported on a covalent triazine-based framework material: an efficient and highly chemoselective catalyst for the reduction of nitroarenes

Author affiliations

Abstract

Pd nanoparticles anchored on a covalent triazine framework (Pd@CTF) were fabricated and employed to catalyze the transfer hydrogenation of nitro-compounds with formic acid as the hydrogen source. The results demonstrated that Pd@CTF displayed excellent catalytic activity and high chemoselectivity for the hydrogenation reaction at room temperature. Various substituted nitro-compounds were successfully converted to the corresponding amines in 0.2–2.5 h with other reducible functional moieties remaining intact. The high performance of Pd@CTF can be attributed to the synergistic interaction between the highly dispersed Pd nanoparticles and the covalent triazine framework support. The Pd@CTF catalyst can be readily reused for at least five consecutive runs without an obvious loss of its catalytic activity.

Graphical abstract: Pd nanoparticles supported on a covalent triazine-based framework material: an efficient and highly chemoselective catalyst for the reduction of nitroarenes

Back to tab navigation

Supplementary files

Publication details

The article was received on 22 Mar 2018, accepted on 29 Apr 2018 and first published on 30 Apr 2018


Article type: Paper
DOI: 10.1039/C8NJ01404C
Citation: New J. Chem., 2018,42, 9684-9689
  •   Request permissions

    Pd nanoparticles supported on a covalent triazine-based framework material: an efficient and highly chemoselective catalyst for the reduction of nitroarenes

    J. Li, L. Zhang, X. Liu, N. Shang, S. Gao, C. Feng, C. Wang and Z. Wang, New J. Chem., 2018, 42, 9684
    DOI: 10.1039/C8NJ01404C

Search articles by author

Spotlight

Advertisements