Issue 14, 2018
From the journal:

New Journal of Chemistry

Two new hexanuclear titanium oxo cluster types and their structural connection to known clusters†‡

Matthias Czakler,a   Christine Artnera  and  Ulrich Schubert ORCID logo *a  

* Corresponding authors

a Institute of Materials Chemistry, Technische Universität Wien, Getreidemarkt 9, 1060 Wien, Austria
E-mail: Ulrich.Schubert@tuwien.ac.at

Abstract

Ti6O6(OiPr)2(OOCR′)10 (R′ = C4H7, Et) and Ti6O3(OiPr)14(OOC–CH[double bond, length as m-dash]CH–COO)2 represent new structure types of carboxylate-substituted clusters with a Ti6Ox core (x = 3–6). They complement the already known six structure types and thus allow conclusions on how the structures of such clusters evolve during substitution and condensation processes.

Graphical abstract: Two new hexanuclear titanium oxo cluster types and their structural connection to known clusters

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Article information

DOI
https://doi.org/10.1039/C8NJ01077C
Article type
Paper
Submitted
08 Mar 2018
Accepted
19 Jun 2018
First published
19 Jun 2018
This article is Open Access
Creative Commons BY license

New J. Chem., 2018,42, 12098-12103

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Two new hexanuclear titanium oxo cluster types and their structural connection to known clusters

M. Czakler, C. Artner and U. Schubert, New J. Chem., 2018, 42, 12098 DOI: 10.1039/C8NJ01077C

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