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Issue 8, 2018
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Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using a Bedford-type palladacycle catalyst

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Abstract

Allylic arylation of cinnamyl acetates with sodium tetraphenylborate using 0.002 mol% of a Bedford-type palladacycle catalyst is described. The developed methodology is applicable for a wide range of cinnamyl acetates furnishing excellent yields of up to 93%. Notably all reactions proceed smoothly under mild reaction conditions in water under an air atmosphere.

Graphical abstract: Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using a Bedford-type palladacycle catalyst

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Publication details

The article was received on 06 Feb 2018, accepted on 17 Mar 2018 and first published on 19 Mar 2018


Article type: Paper
DOI: 10.1039/C8NJ00660A
Citation: New J. Chem., 2018,42, 6210-6214
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    Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using a Bedford-type palladacycle catalyst

    S. A. Ghorpade, D. N. Sawant, D. Renn, A. Zernickel, W. Du, N. Sekar and J. Eppinger, New J. Chem., 2018, 42, 6210
    DOI: 10.1039/C8NJ00660A

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