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Issue 5, 2018
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Concise synthesis of ketoallyl sulfones through an iron-catalyzed sequential four-component assembly

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Abstract

A three starting material four component reaction (3SM-4CR) strategy is described to prepare β-acyl allylic sulfones from methyl ketones, sodium sulfinates and dimethylacetamide (DMA) in an iron-catalyzed oxidative system. In this process, DMA was used as a dual synthon to provide two carbons. A broad range of functional groups were tolerated in this reaction system.

Graphical abstract: Concise synthesis of ketoallyl sulfones through an iron-catalyzed sequential four-component assembly

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Article information


Submitted
11 Dec 2017
Accepted
23 Jan 2018
First published
24 Jan 2018

Green Chem., 2018,20, 973-977
Article type
Communication

Concise synthesis of ketoallyl sulfones through an iron-catalyzed sequential four-component assembly

F. Xiao, C. Liu, D. Wang, H. Huang and G. Deng, Green Chem., 2018, 20, 973
DOI: 10.1039/C7GC03719H

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