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Synthesis and ligand substitution reactions of κ4-B,S,S′,S′′-ruthenaboratranes

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Abstract

A range of ruthenaboratranes of the form [Ru(CO)L{κ4-B,S,S′,S′′-B(mt)3}] (mt = N-methylmercaptoimidazolyl) have been prepared either by substitution of the PPh3 ligand in [Ru(CO)(PPh3){κ4-B,S,S′,S′′-B(mt)3}] by L (L = PMe2Ph, PMe3, P(OMe)3, P(OEt)3, P(OPh)3) or reactions of [RuCl(R)(CO)Ln] (R = Ph, CH[double bond, length as m-dash]CHPh; n = 2, L = PCy3; n = 3, L = P(OMe)3, PMe2Ph) with Na[HB(mt)3].

Graphical abstract: Synthesis and ligand substitution reactions of κ4-B,S,S′,S′′-ruthenaboratranes

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Publication details

The article was received on 26 Oct 2018, accepted on 23 Nov 2018 and first published on 26 Nov 2018


Article type: Paper
DOI: 10.1039/C8DT04278K
Citation: Dalton Trans., 2018, Advance Article
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    Synthesis and ligand substitution reactions of κ4-B,S,S′,S′′-ruthenaboratranes

    M. R. St.-J. Foreman, A. F. Hill, C. Ma, N. Tshabang and A. J. P. White, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT04278K

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