Jump to main content
Jump to site search


Modulation of the mechanical energy storage performance of the MIL-47(VIV) Metal Organic Framework by ligand functionalization

Abstract

The functionalization of the Metal-organic Framework MIL-47(VIV) with ligands bearing bulky functional groups (-Br or -CF3) has been envisaged as a possible route to enhance the mechanical energy storage performances of this family of hybrid porous materials. This exploratory work was carried out by coupling advanced experimental techniques (mercury intrusion and X-ray powder diffraction) supported by Density Functional Theory calculations. MIL-47(VIV)-CF3 was demonstrated to be one of the most promising porous materials for mechanical energy-related applications with performances in terms of work energy which surpasses that of any porous solids reported so far.

Back to tab navigation

Supplementary files

Publication details

The article was received on 22 Oct 2018, accepted on 07 Dec 2018 and first published on 07 Dec 2018


Article type: Paper
DOI: 10.1039/C8DT04214D
Citation: Dalton Trans., 2018, Accepted Manuscript
  •   Request permissions

    Modulation of the mechanical energy storage performance of the MIL-47(VIV) Metal Organic Framework by ligand functionalization

    P. G. Yot, M. Wahiduzzaman, E. Elkaim, P. Fertey, P. Fabry, C. Serre and G. Maurin, Dalton Trans., 2018, Accepted Manuscript , DOI: 10.1039/C8DT04214D

Search articles by author

Spotlight

Advertisements