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Issue 47, 2018
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Platinum-mediated monohydration of SO2

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Abstract

The monohydration of SO2 has been achieved in solution mediated by a platinum-aquo complex. Benzamidate ligands play a key role along the process, acting as versatile proton shuttles. Finally, the platinum center allows the stabilization of benzimidic acid and a hydrogensulphite anion, the disfavored tautomers of benzamide and sulphonate, respectively.

Graphical abstract: Platinum-mediated monohydration of SO2

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Publication details

The article was received on 17 Oct 2018, accepted on 15 Nov 2018 and first published on 15 Nov 2018


Article type: Communication
DOI: 10.1039/C8DT04169E
Dalton Trans., 2018,47, 16846-16849

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    Platinum-mediated monohydration of SO2

    A. Gimeno-Prat, A. Cortés-Sanchón, A. Martín, M. Baya and J. M. Casas, Dalton Trans., 2018, 47, 16846
    DOI: 10.1039/C8DT04169E

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