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Single-molecule magnet behaviour in a Dy(III) pentagonal bipyramidal complex with a quasi-linear Cl–Dy–Cl sequence

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Abstract

We report the synthesis and magnetic investigation of a dysprosium pentagonal bipyramidal complex [Dy(THF)5Cl2][BPh4] (1) exhibiting a linear Cl–Dy–Cl sequence suitable for providing a coordination environment allowing a zero-field slow relaxation of the magnetization. Besides, the complex also shows dual luminescence originating from [BPh4] and Dy3+.

Graphical abstract: Single-molecule magnet behaviour in a Dy(iii) pentagonal bipyramidal complex with a quasi-linear Cl–Dy–Cl sequence

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Publication details

The article was received on 12 Oct 2018, accepted on 07 Nov 2018 and first published on 08 Nov 2018


Article type: Communication
DOI: 10.1039/C8DT04098B
Citation: Dalton Trans., 2018, Advance Article
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    Single-molecule magnet behaviour in a Dy(III) pentagonal bipyramidal complex with a quasi-linear Cl–Dy–Cl sequence

    J. Long, A. N. Selikhov, E. Mamontova, K. A. Lyssenko, Y. Guari, J. Larionova and A. A. Trifonov, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT04098B

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