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NaBaMIIIQ3 (MIII = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q6)6− dimers

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Abstract

In this study, a new series of NaBaMIIIQ3 (MIII = Al, Ga; Q = S, Se) compounds featuring the first discovered isolated edge-shared (MIII2Q6)6− dimers in known quaternary chalcogenides were synthesized. All compounds showed clear optical anisotropy (Δn = 0.04–0.12) mainly derived from the contribution of isolated (MIII2Q6)6− dimers by the real-space atom-cutting method.

Graphical abstract: NaBaMIIIQ3 (MIII = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q6)6− dimers

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Publication details

The article was received on 09 Oct 2018, accepted on 19 Oct 2018 and first published on 22 Oct 2018


Article type: Communication
DOI: 10.1039/C8DT04048F
Citation: Dalton Trans., 2018, Advance Article
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    NaBaMIIIQ3 (MIII = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q6)6− dimers

    A. Abudurusuli, K. Wu, Y. Rouzhahong, Z. Yang and S. Pan, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT04048F

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