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Copper based coordination polymers based on metalloligands: utilization as heterogeneous oxidation catalysts

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Abstract

This work presents the synthesis and characterization of two Cu(II)-based coordination polymers prepared by utilizing two different Co(III)-based metalloligands offering appended arylcarboxylic acid groups. Both coordination polymers are three-dimensional in nature and present pores and channels filled with water molecules. Both coordination polymers function as heterogeneous catalysts for the epoxidation of various olefins using O2 while employing isobutyraldehyde as the coreductor and for peroxide-mediated oxidation of assorted benzyl alcohols. The catalytic results illustrate efficient oxidation reactions, whereas the hot-fltration test and leaching experiments indicate the true heterogeneous nature of the catalysis.

Graphical abstract: Copper based coordination polymers based on metalloligands: utilization as heterogeneous oxidation catalysts

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Publication details

The article was received on 22 Sep 2018, accepted on 02 Nov 2018 and first published on 03 Nov 2018


Article type: Paper
DOI: 10.1039/C8DT03836H
Citation: Dalton Trans., 2018, Advance Article
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    Copper based coordination polymers based on metalloligands: utilization as heterogeneous oxidation catalysts

    G. Kumar, F. Hussain and R. Gupta, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT03836H

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