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PbFePO4F2 with a 1/6th bond depleted triangular lattice

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Abstract

We hydrothermally synthesized a layered PbFePO4F2 (P21/n). Fe3+ cations (S = 5/2) within the layer are connected via F and (PO4)3– anions to give a novel (distorted) 1/6th bond depleted triangular lattice. The χ(T) suggests strong antiferromagnetic interactions with a Weiss constant of −125 K, but geometrical frustration and low dimensionality appear to prohibit a long-range order down to 23 K.

Graphical abstract: PbFePO4F2 with a 1/6th bond depleted triangular lattice

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Publication details

The article was received on 20 Sep 2018, accepted on 08 Oct 2018 and first published on 09 Oct 2018


Article type: Communication
DOI: 10.1039/C8DT03802C
Citation: Dalton Trans., 2018, Advance Article
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    PbFePO4F2 with a 1/6th bond depleted triangular lattice

    H. Lu and H. Kageyama, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT03802C

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