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Issue 45, 2018
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Rh(III)-Catalysed solvent-free hydrodehalogenation of alkyl halides by tertiary silanes

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Abstract

Efficient catalytic reduction of CDCl3 and other alkyl halides, including persistent organic pollutants, by different tertiary silanes using the unsaturated silyl-hydrido-Rh(III) complex {Rh(H)[SiMe2(o-C6H4SMe)](PPh3)2}[BArF4] as a pre-catalyst is accomplished. The reactions are performed in a solvent-free manner. On account of experimental evidence, a simplified catalytic cycle is suggested for the hydrodehalogenation of CDCl3.

Graphical abstract: Rh(iii)-Catalysed solvent-free hydrodehalogenation of alkyl halides by tertiary silanes

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Publication details

The article was received on 13 Sep 2018, accepted on 19 Oct 2018 and first published on 19 Oct 2018


Article type: Paper
DOI: 10.1039/C8DT03703E
Dalton Trans., 2018,47, 16225-16231

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    Rh(III)-Catalysed solvent-free hydrodehalogenation of alkyl halides by tertiary silanes

    N. Almenara, S. Azpeitia, M. A. Garralda and M. A. Huertos, Dalton Trans., 2018, 47, 16225
    DOI: 10.1039/C8DT03703E

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