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Issue 43, 2018
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Water stable oxalate-based coordination polymers with in situ generated cyclic dipeptides showing high proton conductivity

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Abstract

Presented here are two water stable oxalate-based coordination polymers with in situ generated cyclic dipeptides, namely, (C12H16N6O2)[Zn2(C2O4)3] (SCU-63) and Mn(C2O4)(C12H14N6O2) (SCU-66). SCU-63 has a honeycomb-like layer intercalated with protonated cyclic dipeptide cations. SCU-66 has a diamondoid framework containing cyclic dipeptide ligands. The two compounds show high proton conductivity on the order of 10−3 S cm−1 at 85 °C under 98% relative humidity.

Graphical abstract: Water stable oxalate-based coordination polymers with in situ generated cyclic dipeptides showing high proton conductivity

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Publication details

The article was received on 10 Sep 2018, accepted on 02 Oct 2018 and first published on 03 Oct 2018


Article type: Communication
DOI: 10.1039/C8DT03659D
Citation: Dalton Trans., 2018,47, 15288-15292
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    Water stable oxalate-based coordination polymers with in situ generated cyclic dipeptides showing high proton conductivity

    J. Shi, J. Li, H. Zeng, G. Zou, Q. Zhang and Z. Lin, Dalton Trans., 2018, 47, 15288
    DOI: 10.1039/C8DT03659D

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