K11RbB28O48: a new triple-layered borate with an unprecedented [B28O57] fundamental building block

Dequan Jiang; Ying Wang; Bingbing Zhang; Guopeng Han; Zhihua Yang; Shilie Pan

doi:10.1039/C8DT02095G

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K₁₁RbB₂₈O₄₈: a new triple-layered borate with an unprecedented [B₂₈O₅₇] fundamental building block†

Dequan Jiang,^ab Ying Wang,

*^a Bingbing Zhang,^a Guopeng Han,

^ab Zhihua Yang

^a and Shilie Pan

*^a

Author affiliations

* Corresponding authors

^a CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry, CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China
E-mail: wangying@ms.xjb.ac.cn, slpan@ms.xjb.ac.cn
Fax: +86-991-3838957
Tel: +86-991 3674558

^b University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

A new mixed-alkali borate, K₁₁RbB₂₈O₄₈, has been obtained using the high-temperature solution method. It features a new [B₂₈O₅₇] fundamental building block. Meanwhile, these units further polymerize to form unusual triple-layered anionic groups. Thermal analysis, optical property measurement, and theoretical calculations were performed.

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Article information

DOI: https://doi.org/10.1039/C8DT02095G
Article type: Communication
Submitted: 23 May 2018
Accepted: 29 Jun 2018
First published: 30 Jun 2018

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Dalton Trans., 2018,47, 10833-10836

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K₁₁RbB₂₈O₄₈: a new triple-layered borate with an unprecedented [B₂₈O₅₇] fundamental building block

D. Jiang, Y. Wang, B. Zhang, G. Han, Z. Yang and S. Pan, Dalton Trans., 2018, 47, 10833 DOI: 10.1039/C8DT02095G

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