Issue 30, 2018

Redox-induced switch between luminescence and magnetism in a trinuclear cyanide-bridged compound

Abstract

A trinuclear cyanide-bridged luminescent compound, trans-RuII(DMAP)4(CN)2[(PY5Me2)Mn]2[PF6]4 (1-R), and its oxidation product, ferromagnetic trans-RuIII(DMAP)4(CN)2[(PY5Me2)Mn]2-[PF6]5 (1-O), were synthesized and fully characterized. This is the first example of a molecular material showing a redox-controlled transformation between fluorescence and ferromagnetism.

Graphical abstract: Redox-induced switch between luminescence and magnetism in a trinuclear cyanide-bridged compound

Supplementary files

Article information

Article type
Communication
Submitted
11 May 2018
Accepted
22 Jun 2018
First published
27 Jun 2018

Dalton Trans., 2018,47, 9985-9988

Redox-induced switch between luminescence and magnetism in a trinuclear cyanide-bridged compound

X. Zhu, S. Su, Y. Wen, L. Zhang, Y. Yang, X. Wu and T. Sheng, Dalton Trans., 2018, 47, 9985 DOI: 10.1039/C8DT01905C

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