Issue 27, 2018
From the journal:

Dalton Transactions

Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand†‡

Masaichi Saito, ORCID logo *a   Naoki Matsunaga,a   Jumpei Hamada,a   Shunsuke Furukawa, ORCID logo a   Mao Minoura,b   Susann Wegner,c   Juri Barthel ORCID logo d  and  Christoph Janiak ORCID logo c  

* Corresponding authors

a Department of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-okubo, Sakura-ku, Saitama-city, Saitama, Japan
E-mail: masaichi@chem.saitama-u.ac.jp

b Department of Chemistry, College of Science, Rikkyo University, Nishi-ikebukuro, Toshima-ku, Tokyo, Japan

c Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstr. 1, D-40225 Düsseldorf, Germany

d Gemeinschaftslabor für Elektronenmikroskopie RWTH-Aachen, Ernst Ruska-Centrum für Mikroskopie und Spektroskopie mit Elektronen, Forschungszentrum Jülich GmbH, D-52425 Jülich, Germany

Abstract

A neutral heterobimetallic triple-decker stannole complex was prepared by the reaction of an anionic ruthenocene bearing a stannole dianionic ligand with [Rh(cod)Cl]2 (cod = 1,5-cyclooctadiene), and the resulting Ru–Rh complex exhibits an electronic property different from those of the corresponding Ru–Ru and Rh–Rh complexes. The Ru–Rh complex can be decomposed in ionic liquids to metal nanoparticles.

Graphical abstract: Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

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Article information

DOI
https://doi.org/10.1039/C8DT01455H
Article type
Paper
Submitted
13 Apr 2018
Accepted
07 May 2018
First published
10 May 2018

Dalton Trans., 2018,47, 8892-8896

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Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

M. Saito, N. Matsunaga, J. Hamada, S. Furukawa, M. Minoura, S. Wegner, J. Barthel and C. Janiak, Dalton Trans., 2018, 47, 8892 DOI: 10.1039/C8DT01455H

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