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Issue 22, 2018
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A rare example of a compact heteroleptic cyclometalated iridium(iii) complex demonstrating well-separated dual emission

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Abstract

A series of [Ir(C^N)2(NN)][PF6] complexes in which NN is 5-(4-ethynylphenyl)-2,2′-bipyridine has been synthesized and characterized by spectroscopic methods. All novel complexes exhibit unique singlet–triplet dual emission in solution with two well-separated emission bands. The mechanism of dual emission has been elucidated on the basis of experimental data and confirmed by TDDFT calculations.

Graphical abstract: A rare example of a compact heteroleptic cyclometalated iridium(iii) complex demonstrating well-separated dual emission

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Article information


Submitted
06 Apr 2018
Accepted
02 May 2018
First published
02 May 2018

Dalton Trans., 2018,47, 7578-7586
Article type
Paper

A rare example of a compact heteroleptic cyclometalated iridium(III) complex demonstrating well-separated dual emission

A. Yu. Gitlina, M. V. Ivonina, V. V. Sizov, G. L. Starova, A. P. Pushkarev, D. Volyniuk, S. P. Tunik, I. O. Koshevoy and E. V. Grachova, Dalton Trans., 2018, 47, 7578
DOI: 10.1039/C8DT01336E

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