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Issue 22, 2018
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A synthetic NO reduction cycle on a bis(pyrazolato)-bridged dinuclear ruthenium complex including photo-induced transformation

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Abstract

A synthetic NO reduction cycle (2NO + 2H+ + 2e → N2O + H2O) on a dinuclear platform {(TpRu)2(μ-pz)2} (Tp = HB(pyrazol-1-yl)3) was achieved, where an unusual N–N coupling complex was included. Moreover, an interesting photo-induced conversion of the N–N coupling complex to an oxido-bridged complex was revealed.

Graphical abstract: A synthetic NO reduction cycle on a bis(pyrazolato)-bridged dinuclear ruthenium complex including photo-induced transformation

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Publication details

The article was received on 28 Mar 2018, accepted on 27 Apr 2018 and first published on 02 May 2018


Article type: Communication
DOI: 10.1039/C8DT01208C
Citation: Dalton Trans., 2018,47, 7399-7401
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    A synthetic NO reduction cycle on a bis(pyrazolato)-bridged dinuclear ruthenium complex including photo-induced transformation

    Y. Arikawa, J. Hiura, C. Tsuchii, M. Kodama, N. Matsumoto and K. Umakoshi, Dalton Trans., 2018, 47, 7399
    DOI: 10.1039/C8DT01208C

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