Unified meso-pores and dense Cu2+ sites in porous coordination polymers for highly efficient gas storage and separation

Hongliang Lyu; Qiang Zhang; Yang Wang; Jingui Duan

doi:10.1039/C8DT00512E

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Unified meso-pores and dense Cu²⁺ sites in porous coordination polymers for highly efficient gas storage and separation†

Hongliang Lyu,^a Qiang Zhang,^a Yang Wang^a and Jingui Duan

*^a

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* Corresponding authors

^a State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China
E-mail: duanjingui@njtech.edu.cn

Abstract

Unified meso-pores and dense open metal sites (OMS) in porous coordination polymers (PCPs) allow highly promising H₂ and C2-hydrocarbon storage, as well as rapid and efficient C₂H_2/4 enrichment from CO₂ mixtures. The positive function of the OMS, associated with guest thermodynamics, was well revealed by in situ infrared (IR) spectroscopy study.

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Article information

DOI: https://doi.org/10.1039/C8DT00512E
Article type: Communication
Submitted: 07 Feb 2018
Accepted: 27 Feb 2018
First published: 27 Feb 2018

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Dalton Trans., 2018,47, 4424-4427

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Unified meso-pores and dense Cu²⁺ sites in porous coordination polymers for highly efficient gas storage and separation

H. Lyu, Q. Zhang, Y. Wang and J. Duan, Dalton Trans., 2018, 47, 4424 DOI: 10.1039/C8DT00512E

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Dalton Transactions