CO oxidation on SnO2 surfaces enhanced by metal doping

Abstract

Doping metal atoms into a host metal oxide lattice can enhance its catalytic activity by modulating the properties of surface oxygen. Here, Pt-doped antimony–tin oxide (Pt/Sb–SnO₂) was compared with Pt-deposited tin oxide (Pt/SnO₂) and Pt-deposited silica (Pt/SiO₂) for the oxidation of CO and propylene. 0.1 wt% Pt was deposited in all three cases. High angle annular dark field scanning transmission electron microscopy images, diffuse reflectance infrared Fourier transform spectra, pulsed H₂ chemisorption results, and X-ray photoelectron spectra indicated that Pt/Sb–SnO₂ has atomically doped Pt inside the SnO₂ lattice while Pt/SnO₂ has Pt nanoparticles covered with SnO₂ layers and Pt/SiO₂ has Pt nanoparticles exposed at the SiO₂ surface. Pt/Sb–SnO₂ showed the best activity for CO oxidation but the poorest activity for propylene oxidation. Propylene oxidation occurred the least on Pt/Sb–SnO₂ due to the lack of surface Pt sites. CO temperature-programmed reduction and O₂ temperature-programmed desorption results revealed that surface oxygen is the most active on Pt/Sb–SnO₂. The formation of carbonates during CO oxidation was monitored, and Pt/Sb–SnO₂ showed the least amount of surface carbonates with enhanced activity and durability. Doping a minimal amount of precious metal can be an efficient strategy to control the properties of metal oxide catalysts.