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Issue 21, 2018
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Aryne-based strategy in the total synthesis of naturally occurring polycyclic compounds

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Abstract

The total syntheses of polycyclic natural products by exploiting an aryne as the key reactive species are reviewed. A short introduction summarizes the basic reactivities of aryne species as well as the methods for its generation. In the main part, early examples and the recent reports (mainly 2012–present) on the use of arynes in multistep syntheses are described.

Graphical abstract: Aryne-based strategy in the total synthesis of naturally occurring polycyclic compounds

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Publication details

The article was received on 01 May 2018 and first published on 24 Oct 2018


Article type: Review Article
DOI: 10.1039/C8CS00350E
Citation: Chem. Soc. Rev., 2018,47, 8030-8056
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    Aryne-based strategy in the total synthesis of naturally occurring polycyclic compounds

    H. Takikawa, A. Nishii, T. Sakai and K. Suzuki, Chem. Soc. Rev., 2018, 47, 8030
    DOI: 10.1039/C8CS00350E

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