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Issue 21, 2018
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Aryne-based strategy in the total synthesis of naturally occurring polycyclic compounds

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Abstract

The total syntheses of polycyclic natural products by exploiting an aryne as the key reactive species are reviewed. A short introduction summarizes the basic reactivities of aryne species as well as the methods for its generation. In the main part, early examples and the recent reports (mainly 2012–present) on the use of arynes in multistep syntheses are described.

Graphical abstract: Aryne-based strategy in the total synthesis of naturally occurring polycyclic compounds

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Article information


Submitted
01 May 2018
First published
24 Oct 2018

Chem. Soc. Rev., 2018,47, 8030-8056
Article type
Review Article

Aryne-based strategy in the total synthesis of naturally occurring polycyclic compounds

H. Takikawa, A. Nishii, T. Sakai and K. Suzuki, Chem. Soc. Rev., 2018, 47, 8030
DOI: 10.1039/C8CS00350E

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