Jump to main content
Jump to site search

Issue 43, 2018
Previous Article Next Article

Structure-specific chiroptical responses of hollow gold nanoprisms

Author affiliations


Chiroptical responses of plasmonic chiral nanostructures can be controllably tuned by judicious tailoring of their structural parameters. In this article, the chiroptical properties of a newly designed plasmon-supporting nanostructure, chiral hollow gold nanoprisms (HGNs), has been numerically investigated in detail. The most compelling observation is that the CD response and the dissymmetry factor (g, which is a measure of the strength of chiroptical responses) of the chiral HGNs are large and at the same time, highly structure-specific. Also, we observed finite CD activity not only in absorption and scattering but also in the extinction spectra, which is a signature of a typical 3D chiral structure. We show that the chiroptical responses of HGNs can be exponentially enhanced simply by controlling the cavity-position or cavity size. Our results reveal that the structure-specific chiroptical response is a result of structure-dependent interplay between the non-radiative (Ohmic) and radiative losses. We also show that the CD intensity of a suitably designed chiral HGN is higher than other nanoscale metasurfaces of comparable volume. The insights obtained from this comprehensive study assert that this unique chiral nanostructure has great potential for being used in numerous applications.

Graphical abstract: Structure-specific chiroptical responses of hollow gold nanoprisms

Back to tab navigation

Supplementary files

Publication details

The article was received on 20 Aug 2018, accepted on 23 Oct 2018 and first published on 23 Oct 2018

Article type: Paper
DOI: 10.1039/C8CP05298K
Phys. Chem. Chem. Phys., 2018,20, 27675-27683

  •   Request permissions

    Structure-specific chiroptical responses of hollow gold nanoprisms

    B. Hazra, J. Dey and M. Chandra, Phys. Chem. Chem. Phys., 2018, 20, 27675
    DOI: 10.1039/C8CP05298K

Search articles by author