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Dynamic behaviour in nonporous hybrid metal–organic materials via mechanochemical and gas–solid reactions

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Abstract

Nonporous hybrid metal–organic materials self-assembled by a ditopic organic ligand and copper(II) have shown a dynamic behavior by releasing and trapping HCl. The solid-state process involves major structural reorganizations comprising cleavage and formation of coordination and covalent chemical bonds by mechanochemical reactions, heating reactions or chemisorption. Single crystal X-ray diffraction, powder X-ray diffraction and TGA in combination with DFT specific for solid-state systems have been used to study the solid-state reactivity.

Graphical abstract: Dynamic behaviour in nonporous hybrid metal–organic materials via mechanochemical and gas–solid reactions

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Publication details

The article was received on 02 Aug 2018, accepted on 28 Sep 2018 and first published on 28 Sep 2018


Article type: Paper
DOI: 10.1039/C8CE01287C
Citation: CrystEngComm, 2018, Advance Article
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    Dynamic behaviour in nonporous hybrid metal–organic materials via mechanochemical and gas–solid reactions

    F. Guo, H. Wang, A. Famulari, H. Lu and J. Martí-Rujas, CrystEngComm, 2018, Advance Article , DOI: 10.1039/C8CE01287C

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