More versatility than thought: large {Zr26} oxocarboxylate cluster by corner-sharing of standard octahedral subunits

Bahareh Nateghi; Ishtvan Boldog; Konstiantyn V. Domasevitch; Christoph Janiak

doi:10.1039/C8CE01064A

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More versatility than thought: large {Zr₂₆} oxocarboxylate cluster by corner-sharing of standard octahedral subunits†

Bahareh Nateghi,

^a Ishtvan Boldog,

*^a Konstiantyn V. Domasevitch

^b and Christoph Janiak

*^a

Author affiliations

* Corresponding authors

^a Institute of Inorganic Chemistry and Structural Chemistry, Heinrich-Heine-Universität Düsseldorf, Universitätsstr. 1, D-40225 Düsseldorf, Germany
E-mail: ishtvan.boldog@gmail.com, janiak@uni-duesseldorf.de

^b Inorganic Chemistry Department, Taras Shevchenko National University of Kiev, Vladimirskaya Street 64, Kiev 01033, Ukraine

Abstract

The largest known zirconium cluster with an idealized formula of [Zr₂₆O₁₈(OH)₃₀(HCOO)₃₈] was obtained via solvolysis of ZrOCl₂ in DMF/HCOOH. The observed Image ID:c8ce01064a-t1.gif {Zr₆} structural organization suggests generalization, with an outlook for even larger clusters promising in the context of organo–inorganic composites and porous materials including MOFs.

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Article information

DOI: https://doi.org/10.1039/C8CE01064A
Article type: Communication
Submitted: 28 Jun 2018
Accepted: 15 Aug 2018
First published: 15 Aug 2018

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CrystEngComm, 2018,20, 5132-5136

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More versatility than thought: large {Zr₂₆} oxocarboxylate cluster by corner-sharing of standard octahedral subunits

B. Nateghi, I. Boldog, K. V. Domasevitch and C. Janiak, CrystEngComm, 2018, 20, 5132 DOI: 10.1039/C8CE01064A

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