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Issue 44, 2018
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Single-crystal-to-single-crystal desolvation in a Ti32 nanoring cluster

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Abstract

The structures of Ti-oxo clusters were thought to be rigid given the high stability of Ti–O–Ti bonds. A Ti32-oxo nanoring, Ti322-O)83-O)8(L)16(gly)32(glyH)16·12(glyH2)·29(IPA) (L = 4-aminobenzoic acid, glyH2 = ethylene glycol, IPA = isopropanol) (1), experiences an unexpected single-crystal-to-single-crystal desolvation process upon exposure to air, affording another new crystalline phase Ti32-oxo cluster (1-Dry) with a shrunk ring size.

Graphical abstract: Single-crystal-to-single-crystal desolvation in a Ti32 nanoring cluster

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Publication details

The article was received on 03 May 2018, accepted on 13 Oct 2018 and first published on 16 Oct 2018


Article type: Communication
DOI: 10.1039/C8CE00717A
Citation: CrystEngComm, 2018,20, 7062-7065
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    Single-crystal-to-single-crystal desolvation in a Ti32 nanoring cluster

    X. Wang, D. Gui, F. Zhai, H. Li, X. Wang, Y. Wang, L. Chen, T. Zheng, Z. Chai and S. Wang, CrystEngComm, 2018, 20, 7062
    DOI: 10.1039/C8CE00717A

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