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Issue 39, 2018
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Two metal–organic frameworks based on pyridyl–tricarboxylate ligands as size-selective catalysts for solvent-free cyanosilylation reaction

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Abstract

Two new three-dimensional metal–organic frameworks {[(CH3)2NH2]2[TM2(L)2]}n·x(solvent) (FJI-Y7, FJI = Fujian Institute, TM = Zn; FJI-Y8, TM = Cd) have been solvothermally prepared based on multifunctional pyridyl–tricarboxylate ligand 5-(5-carboxypyridin-3-yl)benzene-1,3-dicarboxylic acid (H3L). Single crystal X-ray analysis reveals that they possess non-interpenetrating binodal (4,4)-connected three-dimensional PtS-type networks with the Schläfli point symbol of {42·84}. Interestingly, both FJI-Y7 and FJI-Y8 can be used as highly efficient size-selective heterogeneous catalysts for the solvent-free cyanosilylation of acetaldehydes under mild conditions.

Graphical abstract: Two metal–organic frameworks based on pyridyl–tricarboxylate ligands as size-selective catalysts for solvent-free cyanosilylation reaction

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Publication details

The article was received on 29 Apr 2018, accepted on 24 Jul 2018 and first published on 24 Jul 2018


Article type: Paper
DOI: 10.1039/C8CE00694F
Citation: CrystEngComm, 2018,20, 6070-6076
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    Two metal–organic frameworks based on pyridyl–tricarboxylate ligands as size-selective catalysts for solvent-free cyanosilylation reaction

    Y. Zhang, K. Su, M. Hao, L. Liu, Z. Han and D. Yuan, CrystEngComm, 2018, 20, 6070
    DOI: 10.1039/C8CE00694F

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